Using sheets of aligned carbon nanotubes coated with silicon, scientists at NC State have demonstrated a method for improving the design of rechargeable lithium ion batteries.
The research, published online in Advanced Materials, shows the potential of manufactured sheets of aligned carbon nanotubes coated with silicon, a material with a much higher energy storage capacity than the graphite composites typically used in lithium ion batteries.
“Putting silicon into batteries can produce a huge increase in capacity—10 times greater,” said Dr. Philip Bradford, assistant professor of textile engineering, chemistry and science at NC State. “But adding silicon can also create 10 times the problems.”
One significant challenge in using silicon is that it swells as lithium ion batteries discharge. As the batteries cycle, silicon can break off from the electrode and float around (known as pulverization) instead of staying in place, making batteries less stable.
When the silicon-coated carbon nanotubes were aligned in one direction like a layer of drinking straws laid end to end, the structure allowed for controlled expansion so that the silicon is less prone to pulverization, said Xiangwu Zhang, associate professor of textile engineering, chemistry and science at NC State.
“There’s a huge demand for batteries for cell phones and electric vehicles, which need higher energy capacity for longer driving distances between charges,” Zhang said. “We believe this carbon nanotube scaffolding potentially has the ability to change the industry, although technical aspects will have to be worked out. The manufacturing process we’re using is scalable and could work well in commercial production.”
The research was supported by the Donors to the American Chemical Society Petroleum Research Fund.
Publication: Kun Fu, et al. “Aligned Carbon Nanotube-Silicon Sheets: A Novel Nano-architecture for Flexible Lithium Ion Battery Electrodes,” Advanced Materials, 2013; DOI: 10.1002/adma.201301920
Image: Wiley-VCH Verlag GmbH & Co. KGaA.
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